The thermodynamic resource
When two salt solutions of different concentrations mix, they release Gibbs free energy — the energy available to do useful work at constant temperature and pressure. The textbook estimate is that when fresh river water (effectively 0 g/kg salinity) mixes with seawater (~35 g/kg), the theoretical extractable energy is around 0.8 kWh per cubic metre of fresh water processed, or equivalently across the mixing of about 1.6 kg of freshwater with 4.4 kg of seawater.
Two technologies exist to capture some of this energy without the full mixing-driven dilution loss:
- Pressure-retarded osmosis (PRO) — a semi-permeable membrane between the freshwater and seawater sides lets water diffuse from the dilute side to the concentrated side, pressurising the seawater outflow enough to drive a turbine. The product is mechanical (and hence electrical) power.
- Reverse electrodialysis (RED) — a stack of alternating anion- and cation-exchange membranes, with electrode pairs at the ends; the chemical-potential difference drives ionic migration, generating a stack voltage that decays as current is drawn.
Both technologies are at lab and small-pilot scale. PRO has the larger global installed pilot capacity; RED has been gaining academic interest because it avoids high-pressure components.


